采矿与安全工程学报 ›› 2016, Vol. 33 ›› Issue (3): 557-563.

• 论文 • 上一篇    下一篇

煤的吸附孔结构对瓦斯放散特性影响的实验研究

  

  1. 西安科技大学安全科学与工程学院,陕西 西安 710054
  • 收稿日期:2015-07-13 出版日期:2016-05-15 发布日期:2016-06-03
  • 作者简介:林海飞(1979—),男,山西省天镇县人,博士,副教授,主要从事矿山安全及瓦斯灾害防治方面的研究。
  • 基金资助:

    国家自然科学基金项目(51104118);陕西省科技新星专项项目(2014KJXX69);新疆科技支撑计划项目(201333110)

Experimental study on the effect of adsorption pore structure on gas emission characteristics

  • Received:2015-07-13 Online:2016-05-15 Published:2016-06-03

摘要: 为揭示煤的吸附孔结构对瓦斯放散特性影响机理,选择新疆阜康矿区典型矿井煤样,进行低温氮吸附及瓦斯放散初速度实验,研究了煤的吸附孔特征参数及其对瓦斯放散初速度的影响。结果表明:实验范围内阜康矿区煤的吸附孔中瓦斯的主要放散方式是 Knudsen 及过渡型;吸附孔各参数对瓦斯放散特性的影响不同,平均孔径越大,瓦斯扩散阻力越小,瓦斯放散初速度越大;孔隙及各孔径下的比表面积和孔容越大,瓦斯放散初速度越小;瓦斯放散初速度与微孔和过渡孔的孔容占比为负线性关系,与中孔的孔容占比为正线性关系,与各孔径下比表面积占比无明显关系;煤的孔隙在研究尺度范围内分形特征显著,瓦斯放散初速度随分形维数的增大而线性减小。

关键词: 孔隙结构, 瓦斯放散初速度, 分形维数, 吸附孔

Abstract: To reveal the influencing mechanism of adsorption pore structure on gas emission characteristics of coal, with the typical coal samples from Fukang coal mining area of Xinjiang, low temperature nitrogen adsorption experiment and initial velocity of diffusion of coal gas experiment are carried out. The characteristic parameters of adsorption pore and its influence on initial velocity of diffusion of coal gas are studied. The experimental results have shown that:1) The main transition forms of gas diffusion in adsorption pore are the Knudsen and transition; 2) The parameters of adsorption pore have different influences on gas diffusion characteristics: the greater the average pore diameter is, the smaller the gas diffusion resistance is and the greater the initial velocity of diffusion of coal gas is; the greater the specific surface area, volume of pore and each pore size are, the smaller the initial velocity of diffusion of coal gas is; 3) The initial velocity of diffusion of coal gas has negative liner correlation with proportion of micropore and transition pore volume, positive liner relationship with the proportion of mesopore volume, and no obvious relationship with the proportion of specific surface area of each pore size; 4) In the study range, the fractal characteristics of coal pore are significant, the initial velocity of diffusion of coal gas decreases with the linear increase of fractal dimension.

Key words: pore structure, initial velocity of diffusion of coal gas, fractal dimension, adsorption pore